Mediating Reaction Orthogonality in Polymer and Materials Science

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dc.authorid0000-0003-1858-0691en_US
dc.contributor.authorCorrigan, Nathaniel
dc.contributor.authorÇiftçi, Mustafa
dc.contributor.authorJung, Kenward
dc.contributor.authorBoyer, Cyrille
dc.date.accessioned2021-03-20T20:09:19Z
dc.date.available2021-03-20T20:09:19Z
dc.date.issued2021
dc.departmentBTÜ, Mühendislik ve Doğa Bilimleri Fakültesi, Kimya Bölümüen_US
dc.description.abstractSelective control of chemical reactions is critical for the proper regulation of processes ranging from intricate biological systems to large scale industrial manufacturing. The progression of synthetic chemistry toward the complexity seen in Nature requires increased control over many concurrent chemical reactions in a non-interfering (orthogonal) fashion. Fortunately, the practically endless pool of synthetic chemical reactions developed to date can often be combined in an orthogonal manner to provide elegant solutions to complex chemical problems. In this review, we first highlight some of the many photochemical reactions that have been applied in orthogonal reaction protocols; the highly selective nature of photochemical reactions makes them well-suited for independent activation in the presence of other reaction components. The application of these orthogonal reactions, especially photochemical reactions, for the synthesis and modification of polymers and polymeric materials is also summarized. Importantly, the use of orthogonal chemical reactions can provide additional opportunities for synthesizing advanced and functional polymeric materials compared to traditional synthetic procedures.en_US
dc.description.sponsorshipScientific and Technological Research Council of Turkey (TUBITAK, BIDEB-2219 International Postdoctoral Research Scholarship Programme)Turkiye Bilimsel ve Teknolojik Arastirma Kurumu (TUBITAK)en_US
dc.description.sponsorshipM.C. is grateful for the financial support from the Scientific and Technological Research Council of Turkey (TUBITAK, BIDEB-2219 International Postdoctoral Research Scholarship Programme).en_US
dc.identifier.doi10.1002/anie.201912001en_US
dc.identifier.endpage1781en_US
dc.identifier.issn1433-7851
dc.identifier.issn1521-3773
dc.identifier.issue4en_US
dc.identifier.pmid31667909en_US
dc.identifier.scopusqualityQ1en_US
dc.identifier.startpage1748en_US
dc.identifier.urihttp://doi.org/10.1002/anie.201912001
dc.identifier.urihttps://hdl.handle.net/20.500.12885/368
dc.identifier.volume60en_US
dc.identifier.wosWOS:000569922800001en_US
dc.identifier.wosqualityQ1en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.indekslendigikaynakPubMeden_US
dc.institutionauthorÇiftçi, Mustafa
dc.language.isoenen_US
dc.publisherWiley-V C H Verlag Gmbhen_US
dc.relation.ispartofAngewandte Chemie-International Editionen_US
dc.relation.publicationcategoryDiğeren_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectmaterials scienceen_US
dc.subjectorthogonalityen_US
dc.subjectphotochemistryen_US
dc.subjectpolymer scienceen_US
dc.titleMediating Reaction Orthogonality in Polymer and Materials Scienceen_US
dc.typeReview Articleen_US

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