Comparative Research of Isotherm, Kinetic, and Thermodynamic Studies for Neutral Red Adsorption by Activated Carbon Prepared from Apple Peel

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dc.authorid0000-0001-9884-0961
dc.authorid0000-0002-6756-4973
dc.authorid0000-0003-1861-7757
dc.contributor.authorKul, Ali Riza
dc.contributor.authorKoyuncu, Huelya
dc.contributor.authorTuran, Aysenur
dc.contributor.authorAldemir, Adnan
dc.date.accessioned2026-02-12T21:05:19Z
dc.date.available2026-02-12T21:05:19Z
dc.date.issued2023
dc.departmentBursa Teknik Üniversitesi
dc.description.abstractIn this study, activated carbon (AC) obtained with apple peel was used for removal of Neutral Red (NR) from aqueous solutions. The characterization of AC was evaluated with the Brunauer-Emmett-Teller (BET), Fourier transform infrared spectra (FTIR), X-ray diffraction (XRD), and scanning electron microscopy/energy-dispersive X-ray spectroscopy (SEM/EDX) analyses. Isotherm, kinetic, and thermodynamic parameters were determined for NR removal with AC. Eighteen isotherm models and eight kinetic models were analyzed for three temperatures and six initial dye concentrations. The experimental data best agree with the Langmuir model among the isotherm models, and the maximum adsorption capacity (q(m)) was calculated 142.857 mg/g at 318 K. It was determined that the pseudo-second-order (PSO) model was the best choice among the kinetic models with the highest correlation coefficients. The removal percentage of NR dye with AC obtained 82.13%, 84.79%, and 87.20% for 120 mg/L initial dye concentration at 298 K, 308 K, and 318 K, respectively. The negative free energy, enthalpy, and entropy values of adsorption obtained - 6386 J/mol, 46280 J/mol, and 165.48 J/mol.K for 20 mg/L NR concentration at 318 K, respectively. The results of this separation process shown spontaneous essence, and workability coinciding with the negative free energy and activation energy was found 13.651 kJ/mol. The assessment of the isotherm, kinetic, and thermodynamic results were evaluated with error functions. The highest correlation coefficient (R-2) values and the lowest sum of squares (SS), sum of the square of error (SE), and mean square of error (MSE) values were determined with Langmuir isotherm and PSO kinetic models. This research showed that AC prepared from biomass can be used effectively for wastewater treatment using adsorption technique.
dc.identifier.doi10.1007/s11270-023-06392-8
dc.identifier.issn0049-6979
dc.identifier.issn1573-2932
dc.identifier.issue6
dc.identifier.scopus2-s2.0-85161321913
dc.identifier.scopusqualityQ2
dc.identifier.urihttps://doi.org/10.1007/s11270-023-06392-8
dc.identifier.urihttps://hdl.handle.net/20.500.12885/6896
dc.identifier.volume234
dc.identifier.wosWOS:001004866700004
dc.identifier.wosqualityQ1
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherSpringer Int Publ Ag
dc.relation.ispartofWater Air and Soil Pollution
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WoS_20260212
dc.subjectNeutral Red
dc.subjectActivated carbon
dc.subjectAdsorption
dc.subjectIsotherm
dc.subjectKinetic
dc.subjectThermodynamic
dc.titleComparative Research of Isotherm, Kinetic, and Thermodynamic Studies for Neutral Red Adsorption by Activated Carbon Prepared from Apple Peel
dc.typeArticle

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