Production and characterization of n-halamine based polyvinyl chloride (pvc) nanowebs

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dc.authorid0000-0003-2048-2951en_US
dc.authorid0000-0002-1640-6035en_US
dc.authorscopusid57327745200en_US
dc.authorscopusid57194680814en_US
dc.authorscopusid30767899000en_US
dc.contributor.authorÇobanoğlu, Batuhan
dc.contributor.authorParın, Fatma Nur
dc.contributor.authorYıldırım, Kenan
dc.date.accessioned2022-04-21T06:44:57Z
dc.date.available2022-04-21T06:44:57Z
dc.date.issued2021en_US
dc.departmentBTÜ, Mühendislik ve Doğa Bilimleri Fakültesi, Polimer Malzeme Mühendisliği Bölümüen_US
dc.description.abstractAntibacterial agent N-halamine, 7,7,9,9-tetramethyl-1,3,8-triazaspiro [4.5]-decane-2,4-dione (TTDD), was synthesized, and it was added into the polyvinyl chloride (PVC) nanoweb. A versatile, and relatively simple method, electrospinning, was used to fabricate continuous and uniform nanowebs. 7,7,9,9-tetramethyl-1,3,8-triazaspiro [4.5]-decane-2,4-dione (TTDD) is a cyclic N-halamine that can be chlorinated easily due to three functional groups (imide, amide, and amine). Therefore, TTDD was preferred for PVC regarding having high stability, non-toxic, non-irritant for skin, and renewable. The rechargeable chlorination process was applied to webs using dilute hypochlorite solution. The antibacterial activity of the webs were evaluated using the ASTM 2149 procedure. FTIR, TGA, and SEM were used to investigate the morphology, thermal characteristics, and chemical structures of PVC webs. Scanning electron microscopy (SEM) displayed that the average diameter of the fibers increased with TTDD concentration. The thermal properties of the PVC webs did not changed significantly. All chlorinated webs indicated highly effective antibacterial activities against both Staphylococcus aureus and Escherichia coli with increased inactivation. Furthermore, the antibacterial efficacy of nanowebs is reformed again by the rechargeable process. The rechargeable chlorination capacity of obtained PVC non-wovens is over >60% (within 6 hours, in pH 5), for four rechargeable chlorine cycles. The new antibacterial PVC nanowebs have the potential for especially useful in medical applications.en_US
dc.identifier.doi10.32710/tekstilvekonfeksiyon.717601en_US
dc.identifier.endpage155en_US
dc.identifier.issn13003356
dc.identifier.issue3en_US
dc.identifier.scopusqualityN/Aen_US
dc.identifier.startpage147en_US
dc.identifier.urihttps://hdl.handle.net/20.500.12885/1949
dc.identifier.volume31en_US
dc.identifier.wosqualityN/Aen_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.institutionauthorÇobanoğlu, Batuhan
dc.institutionauthorParın, Fatma Nur
dc.institutionauthorYıldırım, Kenan
dc.language.isoenen_US
dc.publisherEge Universitesien_US
dc.relation.ispartofTekstil ve Konfeksiyonen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.subjectAntibacterial efficiencyen_US
dc.subjectElectrospinningen_US
dc.subjectN-halamineen_US
dc.subjectNanoweben_US
dc.subjectPolyvinylchloride (PVC)en_US
dc.titleProduction and characterization of n-halamine based polyvinyl chloride (pvc) nanowebsen_US
dc.typeArticleen_US

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