Synthesis and Characterization of a New 2-{(E)-[(4-aminophenyl)imino]methyl}-6-bromo-4-chlorophenol and Its Complexes with Co (II), Ni (II), Cu (II), and Zn (II): An Experimental and DFT Study

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dc.authorid0000-0001-6314-3365en_US
dc.contributor.authorBakirdere, Emine Gulhan
dc.contributor.authorFellah, Mehmet Ferdi
dc.contributor.authorCanpolat, Erdal
dc.contributor.authorKaya, Mehmet
dc.date.accessioned2021-03-20T20:15:18Z
dc.date.available2021-03-20T20:15:18Z
dc.date.issued2015
dc.departmentBTÜ, Mühendislik ve Doğa Bilimleri Fakültesi, Kimya Mühendisliği Bölümüen_US
dc.description.abstractThe complexes of Co, Ni, Cu and Zn with 2-{(E)-[(4-aminophenyl)imino]methyl}-6-bromo-4-chlorophenol were prepared and characterized by physical, spectral, and analytical data. The metal:ligand stoichiometric ratio is 1:2 in all the complexes produced. The bidentate behavior of the ligand was accomplished via the phenolic oxygen and the azomethine nitrogen atoms. Suitable structures have been proposed for the complexes synthesized. The theoretically optimized geometries of complexes have tetrahedral structures. The stretching frequencies of CN, CO, and NH were computed to be in good agreement with experimental data. All calculated frequencies fall within 2% of the experimental frequency regions.en_US
dc.description.sponsorshipManagement Unit of Scientific Research Projects of Firat University (FUBAP)Firat University [1276]en_US
dc.description.sponsorshipThe support of the Management Unit of Scientific Research Projects of Firat University (FUBAP) under research project no. 1276 is gratefully acknowledged. The numerical calculations reported in this paper were performed at TUBITAK ULAKBIM, High Performance and Grid Computing Center (TR-Grid e-Infrastructure).en_US
dc.identifier.doi10.1080/15533174.2013.862718en_US
dc.identifier.endpage1346en_US
dc.identifier.issn1553-3174
dc.identifier.issn1553-3182
dc.identifier.issue9en_US
dc.identifier.scopusqualityN/Aen_US
dc.identifier.startpage1337en_US
dc.identifier.urihttp://doi.org/10.1080/15533174.2013.862718
dc.identifier.urihttps://hdl.handle.net/20.500.12885/1177
dc.identifier.volume45en_US
dc.identifier.wosWOS:000354105500012en_US
dc.identifier.wosqualityQ4en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.institutionauthorFellah, Mehmet Ferdi
dc.language.isoenen_US
dc.publisherTaylor & Francis Incen_US
dc.relation.ispartofSynthesis And Reactivity In Inorganic Metal-Organic And Nano-Metal Chemistryen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectSchiff baseen_US
dc.subjecttransition metal complexen_US
dc.subjectDFTen_US
dc.titleSynthesis and Characterization of a New 2-{(E)-[(4-aminophenyl)imino]methyl}-6-bromo-4-chlorophenol and Its Complexes with Co (II), Ni (II), Cu (II), and Zn (II): An Experimental and DFT Studyen_US
dc.typeArticleen_US

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