Synthesis and Characterization of a New 2-{(E)-[(4-aminophenyl)imino]methyl}-6-bromo-4-chlorophenol and Its Complexes with Co (II), Ni (II), Cu (II), and Zn (II): An Experimental and DFT Study
Küçük Resim Yok
Tarih
2015
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Taylor & Francis Inc
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
The complexes of Co, Ni, Cu and Zn with 2-{(E)-[(4-aminophenyl)imino]methyl}-6-bromo-4-chlorophenol were prepared and characterized by physical, spectral, and analytical data. The metal:ligand stoichiometric ratio is 1:2 in all the complexes produced. The bidentate behavior of the ligand was accomplished via the phenolic oxygen and the azomethine nitrogen atoms. Suitable structures have been proposed for the complexes synthesized. The theoretically optimized geometries of complexes have tetrahedral structures. The stretching frequencies of CN, CO, and NH were computed to be in good agreement with experimental data. All calculated frequencies fall within 2% of the experimental frequency regions.
Açıklama
Anahtar Kelimeler
Schiff base, transition metal complex, DFT
Kaynak
Synthesis And Reactivity In Inorganic Metal-Organic And Nano-Metal Chemistry
WoS Q Değeri
Q4
Scopus Q Değeri
N/A
Cilt
45
Sayı
9
