Exploring Hierarchically Porous Functional PolyHIPEs for Polymeric Support Designs: Synergistic Effects of VBC Content and Crosslinking on Surface Properties

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dc.authorid0000-0001-7228-2340
dc.authorid0000-0003-1365-7928
dc.contributor.authorSuslukaya, Merve
dc.contributor.authorDeniz, Erhan
dc.contributor.authorKaya, Yunus
dc.date.accessioned2026-02-08T15:14:45Z
dc.date.available2026-02-08T15:14:45Z
dc.date.issued2025
dc.departmentBursa Teknik Üniversitesi
dc.description.abstractIn this study, high internal phase emulsions (HIPEs) with ranging vinyl benzyl chloride (VBC) contents (50-80 v/v%) were prepared to synthesize polyHIPEs with 90% nominal porosity having different ratios of -Cl content. The resulting polyHIPEs were then hypercrosslinked for a duration of either 15 or 30 min through Friedel-Crafts alkylation reaction. The chemical and morphological properties of the materials have been characterized by FTIR analysis, SEM image analysis, EDS surface mapping and elemental analysis, Mohr's precipitation titration for -Cl (wt%) content determination, surface area and porosity analysis by using N2 adsorption/desorption isotherms, TGA analysis, and WCA measurements. It has been shown that the optimal VBC and DVB monomer phase ratios (v/v) which yield the highest BET surface area (SBET) were found to be 7/10 and 0.6/10, respectively. Hierarchically porous functional polyHIPEs possessing tunable surface area (SBET = 5.30-851.33 m2 g-1) with uniform micro-meso pore (1.31-9.91 nm) distribution and -Cl content (2.13-17.81 w/w%) exhibited high temperature stability and oleophilicity.
dc.description.sponsorshipIndustrial PhD Fellowship Program of the Turkiye Bilimsel ve Teknolojik Arastimath;rma Kurumu (TUBIdot;TAK) [119C042]; Scientific Research Projects Coordination: Bursa Technical University [240D009]
dc.description.sponsorshipThis work was supported by the Industrial PhD Fellowship Program of the Turkiye Bilimsel ve Teknolojik Arast & imath;rma Kurumu (TUB & Idot;TAK) (Grant 119C042) and the Scientific Research Projects Coordination: Bursa Technical University (Grant 240D009).
dc.identifier.doi10.1002/app.57598
dc.identifier.issn0021-8995
dc.identifier.issn1097-4628
dc.identifier.issue41
dc.identifier.scopus2-s2.0-105009912933
dc.identifier.scopusqualityQ2
dc.identifier.urihttps://doi.org/10.1002/app.57598
dc.identifier.urihttps://hdl.handle.net/20.500.12885/5410
dc.identifier.volume142
dc.identifier.wosWOS:001523812500001
dc.identifier.wosqualityQ3
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherWiley
dc.relation.ispartofJournal of Applied Polymer Science
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/openAccess
dc.snmzWOS_KA_20260207
dc.subjectcatalysts
dc.subjectfunctional organic polymers
dc.subjectheterogeneous catalyst support
dc.subjecthierarchically porous polymers
dc.subjecthypercrosslinking
dc.subjectmorphology
dc.subjectpolyHIPE
dc.subjectporous materials
dc.subjectstructure-property relationships
dc.titleExploring Hierarchically Porous Functional PolyHIPEs for Polymeric Support Designs: Synergistic Effects of VBC Content and Crosslinking on Surface Properties
dc.typeArticle

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