Block Copolymers by Mechanistic Transformation from PROAD to Iniferter Process

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dc.authorid0000-0003-1858-0691en_US
dc.contributor.authorÇiftçi, Mustafa
dc.contributor.authorYagci, Yusuf
dc.date.accessioned2021-03-20T20:13:04Z
dc.date.available2021-03-20T20:13:04Z
dc.date.issued2018
dc.departmentBTÜ, Mühendislik ve Doğa Bilimleri Fakültesi, Kimya Bölümüen_US
dc.description.abstractA facile strategy for synthesizing block copolymers by the combination of two different living polymerization techniques, namely, photoinduced radical oxidation/addition/deactivation (PROAD) and iniferter processes is described. In the first step, PROAD polymerization of isobutyl vinyl ether using bromotriphenylmethane, dimanganese decacarbonyl (Mn-2(CO)(10)), and diphenyliodonium bromide (Ph2I+Br-) is carried out to yield polymers with triphenylmethyl (trityl) end groups. These prepolymers are used as macroiniferters in thermally induced free radical polymerization of vinyl monomers such as methyl methacrylate, tert-butyl acrylate, and styrene, resulting in the formation of corresponding block copolymers free from homopolymers. The precursor polymer and final block copolymers are characterized by H-1 NMR, FT-IR, GPC, and DSC analyses.en_US
dc.identifier.doi10.1002/marc.201800464en_US
dc.identifier.issn1022-1336
dc.identifier.issn1521-3927
dc.identifier.issue18en_US
dc.identifier.pmid30091815en_US
dc.identifier.scopusqualityQ1en_US
dc.identifier.urihttp://doi.org/10.1002/marc.201800464
dc.identifier.urihttps://hdl.handle.net/20.500.12885/781
dc.identifier.volume39en_US
dc.identifier.wosWOS:000444956700008en_US
dc.identifier.wosqualityQ1en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.indekslendigikaynakPubMeden_US
dc.institutionauthorÇiftçi, Mustafa
dc.language.isoenen_US
dc.publisherWiley-V C H Verlag Gmbhen_US
dc.relation.ispartofMacromolecular Rapid Communicationsen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectblock copolymersen_US
dc.subjectcationic polymerizationen_US
dc.subjectfree radical polymerizationen_US
dc.subjectinifertersen_US
dc.subjectmechanistic transformationen_US
dc.subjectphotoinduced radical oxidation/addition/deactivationen_US
dc.titleBlock Copolymers by Mechanistic Transformation from PROAD to Iniferter Processen_US
dc.typeArticleen_US

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