Evaluation of the use and performance of natural filler based polypropylene/leonardite composites

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dc.authorid0000-0002-4406-9048
dc.authorid0000-0003-2733-7191
dc.authorid0000-0002-8113-5534
dc.contributor.authorSen, Ibrahim
dc.contributor.authorTuna, Sibel
dc.contributor.authorKurtlu, Meral Akkoyun
dc.date.accessioned2026-02-08T15:15:19Z
dc.date.available2026-02-08T15:15:19Z
dc.date.issued2024
dc.departmentBursa Teknik Üniversitesi
dc.description.abstractThe use of polypropylene (PP), which has reached a considerably high level in the last century and is one of the polymers whose properties have been investigated and studied in much more detail with the use of various additives, can be obtained as composite structures with the use of both inorganic and organic additives, and the desired properties can be modified according to the desired purpose. In this study, it was aimed to evaluate the behavior of leonardite, a rich source of humic acid, with PP composite structures, whose performance with thermoplastic materials has never been investigated before, although there are studies on its use in different sectors. To evaluate the effects of different ratios of leonardite additives on PP polymer, the composites were prepared with a twin screw extruder, and the test specimens were produced using an injection molding device. Spectroscopic, density, microscopic, mechanical (tensile, impact, flexural), thermal and color analyses of composites containing leonardite at 0, 0.5, 1, 3, 5, and 10 wt% were carried out. As the amount of leonardite in the composite increased, a slight increase was observed in the density values of the composites, with a maximum of 4.7%. In microstructure analysis, a homogeneous distribution of the filler was observed in composites reinforced up to 1 wt%, while agglomeration occurred at higher rates. While the highest tensile strength and flexural strength values were found for the 5 wt% leonardite filled composite, it was observed that these values increased from 31.8 MPa to 32.7 MPa and from 32.84 MPa to 37.84 MPa compared to the pure PP, respectively. The highest Izod impact strength value was determined for the 10 wt% leonardite filled composite and an increase in this value was obtained from 2.47 kJ/m2 to 2.85 kJ/m2. The nucleation effect explains the decrease in supercooling temperature observed in the thermal analysis results. Furthermore, an increase of the thermal stability of PP/leonardite composite structures was demonstrated. When the color analysis results were examined, it was seen that the leonardite additive caused the color of the composite to darken, as expected.
dc.identifier.doi10.1016/j.jclepro.2024.144105
dc.identifier.issn0959-6526
dc.identifier.issn1879-1786
dc.identifier.scopus2-s2.0-85207541461
dc.identifier.scopusqualityQ1
dc.identifier.urihttps://doi.org/10.1016/j.jclepro.2024.144105
dc.identifier.urihttps://hdl.handle.net/20.500.12885/5719
dc.identifier.volume480
dc.identifier.wosWOS:001348394500001
dc.identifier.wosqualityQ1
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherElsevier Sci Ltd
dc.relation.ispartofJournal of Cleaner Production
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/openAccess
dc.snmzWOS_KA_20260207
dc.subjectNatural filler based composites
dc.subjectLeonardite
dc.subjectPolypropylene
dc.titleEvaluation of the use and performance of natural filler based polypropylene/leonardite composites
dc.typeArticle

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