Advances in PEKK Thermoplastic Composites: Reinforcing With MWCNTs and GNPs for Enhanced Performance
Küçük Resim Yok
Tarih
2025
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Wiley
Erişim Hakkı
info:eu-repo/semantics/openAccess
Özet
Polyetherketoneketone (PEKK) is a highly regarded material in polymer science due to its outstanding thermal stability, mechanical strength, and chemical resistance. Despite substantial research on PEKK composites reinforced with CNTs and GNPs, two primary challenges remain: inconsistent glass transition temperature behavior at varying filler contents, leading to unpredictable shifts in both thermal and mechanical performance, and the absence of direct comparisons under uniform processing conditions that would allow quantitative evaluation of each filler's effect. In this work, PEKK/MWCNT and PEKK/GNP nanocomposites were produced via the same hot-press molding protocol and systematically evaluated for thermal and mechanical performance, electrical conductivity (using S-value analysis) and microstructural morphology. A range of mechanical tests, including tensile, Charpy impact, and hardness tests, were conducted alongside physical analyses such as differential scanning calorimetry (DSC), thermogravimetric analysis, dynamic mechanical analysis (DMA), thermal conductivity, electrical conductivity, and scanning electron microscopy (SEM). The results demonstrated that both MWCNTs and GNPs significantly enhanced PEKK's properties. The incorporation of MWCNTs raised the glass transition temperature (T-g) to 169 degrees C and the crystallization temperature (T-c) to 327 degrees C, whereas GNPs increased the decomposition temperature (T-d) to 572 degrees C. Adding 1 wt.% of either nano-additive notably improved tensile and flexural strength, while an optimal concentration of 0.1 wt.% was determined for Charpy impact performance. Additionally, higher concentrations resulted in exceptional electrical and thermal conductivity.
Açıklama
Anahtar Kelimeler
GNP, MWCNT, nanocomposite, PEKK
Kaynak
Polymers For Advanced Technologies
WoS Q Değeri
Q2
Scopus Q Değeri
Q2
Cilt
36
Sayı
7
