Impact of PCE-based grinding aids on hydration kinetics in fly ash substituted systems: Influence of pH and dosage

dc.authorid0000-0003-0326-5015
dc.contributor.authorKaya, Yahya
dc.contributor.authorKobya, Veysel
dc.contributor.authorKaya, Yunus
dc.contributor.authorMardani, Ali
dc.date.accessioned2026-02-08T15:15:10Z
dc.date.available2026-02-08T15:15:10Z
dc.date.issued2025
dc.departmentBursa Teknik Üniversitesi
dc.description.abstractWhile the use of grinding aids (GAs) is commonly favored for their cost and energy efficiency benefits, these additives can also present challenges, such as incompatibility with water-reducing admixtures. This has led to interest in polycarboxylate-based water-reducing admixtures (PCEs) as potential grinding aid (GA). However, there is a significant gap in the literature concerning the interaction between these PCE-based GA properties and cementitious systems' morphological characteristics and hydration kinetics. This study investigated the effects of PCE-based GAs with varying pH levels on hydration kinetics, flowability, and compressive strength in cementitious systems containing fly ash. PCE-based GAs were synthesized at three different pH levels (4, 7, 9), while other parameters were held constant. Using these GAs, a total of 10 Portland cements, including one control, were produced at three different dosages. Additionally, two different fly ash substitution levels were used to prepare paste and mortar mixtures with these cements. This approach has enabled the investigation of fly ash substitution systems in the presence of PCE-based GAs and the assessment of environmental impact through life cycle analysis. The study aimed to contribute to the existing literature and offer an alternative approach to sustainable production. The findings revealed that the PCE-based GA with a low pH value (4) was the most optimal in terms of the evaluated properties.
dc.description.sponsorshipScientific and Technological Research Council of Turkey (TUBITAK) [222M245]; Bursa Uludag University Science and Technology Centre (BAP) [FGA-2024-1754, FGA-2022-1151]; TUBITAK
dc.description.sponsorshipThe authors wish to acknowledge the support of the Scientific and Technological Research Council of Turkey (TUBITAK) through grant Number: 222M245. They also extend their thanks to the Bursa Uludag University Science and Technology Centre (BAP) for their contributions under grant number FGA-2024-1754 and FGA-2022-1151. Additionally, the lead author expresses gratitude to TUBITAK for awarding the 2211 A scholarship during their doctoral studies.
dc.identifier.doi10.1016/j.conbuildmat.2024.139531
dc.identifier.issn0950-0618
dc.identifier.issn1879-0526
dc.identifier.scopus2-s2.0-85211748070
dc.identifier.scopusqualityQ1
dc.identifier.urihttps://doi.org/10.1016/j.conbuildmat.2024.139531
dc.identifier.urihttps://hdl.handle.net/20.500.12885/5646
dc.identifier.volume458
dc.identifier.wosWOS:001388441900001
dc.identifier.wosqualityQ1
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherElsevier Sci Ltd
dc.relation.ispartofConstruction and Building Materials
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzWOS_KA_20260207
dc.subjectPCE-based GA pH
dc.subjectHydration kinetics
dc.subjectLife cycle
dc.titleImpact of PCE-based grinding aids on hydration kinetics in fly ash substituted systems: Influence of pH and dosage
dc.typeArticle

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