Design, synthesis, characterization, and antimicrobial activity of the new 2-{(E)-[(4-aminophenyl)imino]methyl}-4,6-dichlorophenol and its complexes with Co(II), Ni(II), Cu(II) and Zn(II): An experimental and DFT study

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dc.authorid0000-0001-6314-3365en_US
dc.contributor.authorBakirdere, Emine Gulhan
dc.contributor.authorFellah, Mehmet Ferdi
dc.contributor.authorCanpolat, Erdal
dc.contributor.authorKaya, Mehmet
dc.contributor.authorGur, Seher
dc.date.accessioned2021-03-20T20:14:50Z
dc.date.available2021-03-20T20:14:50Z
dc.date.issued2016
dc.departmentBTÜ, Mühendislik ve Doğa Bilimleri Fakültesi, Kimya Mühendisliği Bölümüen_US
dc.description.abstractIn this study, the complexes of Co(II), Ni(II), Cu(II) and Zn(II) with 2-{(E)-[(4-aminophenyl)imino]methyl}-4,6-dichlorophenol were prepared and characterized by physical, spectral and analytical data. The metal:ligand stoichiometric ratio was 1:2 in all the complexes. The results suggested that the Schiff bases were coordinated to the metal ions through the phenolic oxygens and the azomethine nitrogen to give mononuclear complexes. Their structures were elucidated based on elemental analysis, IR, H-1- and C-13-NMR, UV-Vis, and magnetic susceptibility measurements and thermogravimetric analyses. Both the antibacterial and antifungal activities and the minimum inhibitory concentration (MIC) values of compounds are reported. Among the tested compounds, the most effective compound providing an MIC value of 64 mu g mL(-1) was Zn(L)(2) against Candida tropicalis and Bacillus subtilis. The theoretically optimized geometries of the complexes were tetrahedral structures. The computed stretching frequencies of the C=N, C-O and N-H bonds were in good agreement with the experimental data. All the calculated frequencies fell within about 5 % of the experimental frequency regions.en_US
dc.description.sponsorshipManagement Unit of Scientific Research Projects of Firat UniversityFirat University [FUBAP 1276]en_US
dc.description.sponsorshipThis work was supported by the Management Unit of Scientific Research Projects of Firat University (Project: FUBAP 1276).en_US
dc.identifier.doi10.2298/JSC151030008Ben_US
dc.identifier.endpage520en_US
dc.identifier.issn0352-5139
dc.identifier.issue5en_US
dc.identifier.scopusqualityQ3en_US
dc.identifier.startpage509en_US
dc.identifier.urihttp://doi.org/10.2298/JSC151030008B
dc.identifier.urihttps://hdl.handle.net/20.500.12885/1113
dc.identifier.volume81en_US
dc.identifier.wosWOS:000379232800004en_US
dc.identifier.wosqualityQ4en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.institutionauthorFellah, Mehmet Ferdi
dc.language.isoenen_US
dc.publisherSerbian Chemical Socen_US
dc.relation.ispartofJournal Of The Serbian Chemical Societyen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.subjectSchiff baseen_US
dc.subjecttransition metal complexen_US
dc.subjectantibacterial and antifungal activitiesen_US
dc.subjectDFTen_US
dc.titleDesign, synthesis, characterization, and antimicrobial activity of the new 2-{(E)-[(4-aminophenyl)imino]methyl}-4,6-dichlorophenol and its complexes with Co(II), Ni(II), Cu(II) and Zn(II): An experimental and DFT studyen_US
dc.typeArticleen_US

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