Effects of junction angle and gas pressure on polymer nanosphere preparation from microbubbles bursted in a combined microfluidic device with thin capillaries

dc.authorid0000-0002-1284-8880en_US
dc.contributor.authorKüçük, İsrafil
dc.contributor.authorYilmaz, Necip Fazil
dc.contributor.authorSinan, Aussama
dc.date.accessioned2021-03-20T20:12:54Z
dc.date.available2021-03-20T20:12:54Z
dc.date.issued2018
dc.departmentBTÜ, Mühendislik ve Doğa Bilimleri Fakültesi, Metalurji ve Malzeme Mühendisliği Bölümüen_US
dc.description.abstractThis study describes polymethylsilsesquioxane (PMSQ) nanospheres preparation from microbubble bursting in a 100 mu m capillaries embedded combined microfluidic device based on effects of junction angle and flow rate of liquid solution. The effects of the junction angle (phi = 0 degrees-60 degrees) between the liquid and gas channels and the gas pressure ratios (50-400 kPa) are considered. The digital microscope results indicate that the microbubble size during the bubble generation process generally decreases with the increase of junction angle at the same flow rate and gas pressure. In addition, the nanosphere size in the combined microfluidic junction device with 100 gm capillaries decreases as junction angle increases with the same flow and gas pressure conditions. When junction angle is about 60 degrees, there always exists the smallest nanosphere formation in the device with thin capillaries used. The microbubble formation in the device used in this work depends significantly on the gas pressure, and the combined microfluidic junction device with thin capillaries becomes a microbubble generation when N-2 gas pressure is greater than 50 kPa at the same junction angle and liquid flow rate. Furthermore, the resulting microbubble and polymer nanosphere size in the device used decreases with an increase of N-2 gas pressure. To evaluate chemical structure of the polymers used before and after the microfluidic processing, PMSQ raw materials and the resultant Polymer nanospheres obtained were also characterised using an MR spectroscopy. The understanding of polymer nanosphere generation from microbubble bursting in the device with thin capillaries used could be very useful for many applications, such as cell transplantation in biomedical therapy, advanced therapeutic applications and food industry. (C) 2018 Elsevier B.V. All rights reserved.en_US
dc.description.sponsorshipGaziantep University Research Uniten_US
dc.description.sponsorshipThe authors would like to acknowledge the support of Gaziantep University Research Unit for funding this research work.en_US
dc.identifier.doi10.1016/j.molstruc.2018.06.084en_US
dc.identifier.endpage427en_US
dc.identifier.issn0022-2860
dc.identifier.issn1872-8014
dc.identifier.scopusqualityQ2en_US
dc.identifier.startpage422en_US
dc.identifier.urihttp://doi.org/10.1016/j.molstruc.2018.06.084
dc.identifier.urihttps://hdl.handle.net/20.500.12885/738
dc.identifier.volume1173en_US
dc.identifier.wosWOS:000446286200048en_US
dc.identifier.wosqualityQ3en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.institutionauthorKüçük, İsrafil
dc.language.isoenen_US
dc.publisherElsevier Science Bven_US
dc.relation.ispartofJournal Of Molecular Structureen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectMicrobubble generationen_US
dc.subjectCombined microfluidic junction deviceen_US
dc.subjectJunction angleen_US
dc.subjectGas pressureen_US
dc.subjectPolymer nanospheresen_US
dc.titleEffects of junction angle and gas pressure on polymer nanosphere preparation from microbubbles bursted in a combined microfluidic device with thin capillariesen_US
dc.typeArticleen_US

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