Electrochemical characterization of poly(thiophene-3-boronic acid) for aqueous environments
Küçük Resim Yok
Tarih
2024
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Elsevier
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
Poly(thiophene-3-boronic acid) (PTBA) was studied as a promising active material for aqueous environments in this paper. Using cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS), the solubility and electrochemical behavior of it was studied in a range of aqueous solutions. Fourier Transform Infrared Spectrometry (FTIR) results verify the successful synthesis. PTBA shows promising solubility qualities in certain pH ranges, especially in alkaline solutions. However, among alkaline, neutral, and acidic environments the best environment for redox properties of aqueous 1 mM PTBA is the neutral one. The peak current (ip) of 1 mM PTBA for 100 mV/s in the neutral environment is 0.01 mA and half peak potential (Ep/2) is _ 0.1 V (vs Ag/AgCl). Diffusion coefficient of PTBA is found as 4.97 x 10_8 cm2/s. The impedance tests also confirm that the neutral solvent decreases the charge transfer resistance.
Açıklama
Anahtar Kelimeler
Poly(thiophene-3-boronic acid), CV, EIS, Water solubility, Flow batteries
Kaynak
Solid State Ionics
WoS Q Değeri
Q2
Scopus Q Değeri
Q2
Cilt
413
