Metal-free ATRP and ROP for graft copolymers: an orthogonal strategy for sequential and concurrent polymerizations at room temperature

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dc.authorid0000-0003-3509-998X
dc.authorid0000-0003-1858-0691
dc.contributor.authorAkyel, Cansu
dc.contributor.authorOrmanci, Ahmet
dc.contributor.authorCiftci, Mustafa
dc.date.accessioned2026-02-08T15:14:48Z
dc.date.available2026-02-08T15:14:48Z
dc.date.issued2026
dc.departmentBursa Teknik Üniversitesi
dc.description.abstractWell-defined poly[(methyl acrylate)-co-(hydroxyethyl acrylate)]-graft-) copolymers were synthesized using a completely metal-free strategy by combining atom transfer radical polymerization (ATRP) and ring-opening polymerization (ROP) at ambient temperature. These two orthogonal, metal-free, controlled/living processes, tested in both simultaneous and sequential approaches, were employed to fine-tune grafting density and efficiency by systematically varying monomer concentration and polymerization time. Spectroscopic and chromatographic characterizations confirmed that both ATRP and ROP proceeded in a controlled fashion, yielding graft copolymers with narrowly distributed molecular weights.
dc.identifier.doi10.1002/pi.70031
dc.identifier.endpage79
dc.identifier.issn0959-8103
dc.identifier.issn1097-0126
dc.identifier.issue2
dc.identifier.scopus2-s2.0-105013643275
dc.identifier.scopusqualityQ1
dc.identifier.startpage75
dc.identifier.urihttps://doi.org/10.1002/pi.70031
dc.identifier.urihttps://hdl.handle.net/20.500.12885/5449
dc.identifier.volume75
dc.identifier.wosWOS:001551805200001
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherWiley
dc.relation.ispartofPolymer International
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzWOS_KA_20260207
dc.subjectmetal-free ATRP
dc.subjectring-opening polymerization
dc.subjectgraft copolymers
dc.titleMetal-free ATRP and ROP for graft copolymers: an orthogonal strategy for sequential and concurrent polymerizations at room temperature
dc.typeArticle

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