Synthesis of graft copolymers by combination of radical photopolymerization and iniferter process

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dc.authorid0000-0003-1858-0691en_US
dc.contributor.authorÇiftçi, Mustafa
dc.date.accessioned2021-03-20T20:12:35Z
dc.date.available2021-03-20T20:12:35Z
dc.date.issued2019
dc.departmentBTÜ, Mühendislik ve Doğa Bilimleri Fakültesi, Kimya Bölümüen_US
dc.description.abstractVarious PS-based graft copolymers including polystyrene-graft-poly(methyl methacrylate) and poly(styrene-graft-poly(ethylene glycol) methacrylate) are prepared via subsequent visible light radical photopolymerization and iniferter processes. Thus, poly(styrene-co-4-chloromethylstyrene) P(S-co-VBC) is synthesized by light induced free-radical polymerization. Then, chloride moieties are substituted with triphenylmethyl (trityl) groups to give trityl-substituted PS (PS-trityl) under visible light irradiation using dimanganese decacarbonyl (Mn-2(CO)(10)) photochemistry. Side chains are then grafted from PS-trityl backbone via iniferter process to give desired graft copolymers in a controlled manner. The precursor intermediates and the final graft copolymers are analyzed by H-1 NMR, FT-IR, and GPC measurements. (c) 2019 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2019, 57, 1344-1348en_US
dc.identifier.doi10.1002/pola.29395en_US
dc.identifier.endpage1348en_US
dc.identifier.issn0887-624X
dc.identifier.issn1099-0518
dc.identifier.issue12en_US
dc.identifier.scopusqualityN/Aen_US
dc.identifier.startpage1344en_US
dc.identifier.urihttp://doi.org/10.1002/pola.29395
dc.identifier.urihttps://hdl.handle.net/20.500.12885/623
dc.identifier.volume57en_US
dc.identifier.wosWOS:000469938700010en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.institutionauthorÇiftçi, Mustafa
dc.language.isoenen_US
dc.publisherWileyen_US
dc.relation.ispartofJournal Of Polymer Science Part A-Polymer Chemistryen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectdimanganese decacarbonylen_US
dc.subjectgraft copolymersen_US
dc.subjectgrafting fromen_US
dc.subjectiniferteren_US
dc.subjectmechanistic transformationen_US
dc.titleSynthesis of graft copolymers by combination of radical photopolymerization and iniferter processen_US
dc.typeArticleen_US

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