Visible light induced one-pot synthesis of amphiphilic hyperbranched copolymers

Basit Öğe Kaydı
dc.authorid0000-0003-1858-0691en_US
dc.contributor.authorAydogan, Cansu
dc.contributor.authorÇiftçi, Mustafa
dc.contributor.authorAsiri, Abdullah Mohamed
dc.contributor.authorYagci, Yusuf
dc.date.accessioned2021-03-20T20:12:55Z
dc.date.available2021-03-20T20:12:55Z
dc.date.issued2018
dc.departmentBTÜ, Mühendislik ve Doğa Bilimleri Fakültesi, Kimya Bölümüen_US
dc.description.abstractDimanganese decacarbonyl (Mn-2(CO)(10)) and alkyl halide combination has unique visible light radical generating property which is useful in the fabrication of many complex macromolecular structures. Herein, we present a generic simple and rapid synthetic approach for the preparation amphiphilic hyperbranched macromolecular structures with controlled branching density and hydrophilicity. The method is based on the visible light induced self-condensing vinyl copolymerization of methyl methacrylate (MMA), 2-(2-bromoisobutryloxy) ethyl methacrylate (BIBEM) and poly(ethylene glycol) methyl ether methacrylate as monomer, inimer and hydrophilic comonomer, respectively, in the presence of Mn-2(CO)(10). The resulting polymers possess both hydrophobic and hydrophilic sequences offering many potential bio applications such as controlled drug delivery and release. Moreover, the resulting polymers contain also unreacted bromide groups in the final structure which allow postfunctionalization through copper(I)-catalyzed alkyne-azide cycloaddition "click" reactions.en_US
dc.identifier.doi10.1016/j.polymer.2018.10.058en_US
dc.identifier.endpage95en_US
dc.identifier.issn0032-3861
dc.identifier.issn1873-2291
dc.identifier.scopusqualityQ1en_US
dc.identifier.startpage90en_US
dc.identifier.urihttp://doi.org/10.1016/j.polymer.2018.10.058
dc.identifier.urihttps://hdl.handle.net/20.500.12885/739
dc.identifier.volume158en_US
dc.identifier.wosWOS:000450910100013en_US
dc.identifier.wosqualityQ1en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.institutionauthorÇiftçi, Mustafa
dc.language.isoenen_US
dc.publisherElsevier Sci Ltden_US
dc.relation.ispartofPolymeren_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectVisible lighten_US
dc.subjectPhotopolymerizationen_US
dc.subjectSelf-condensing vinyl polymerizationen_US
dc.subjectHyperbranched polymersen_US
dc.subjectAmphiphilic copolymersen_US
dc.titleVisible light induced one-pot synthesis of amphiphilic hyperbranched copolymersen_US
dc.typeArticleen_US

Dosyalar

Koleksiyon

WoS İndeksli Yayınlar Koleksiyonu
Kimya Bölümü Yayın Koleksiyonu
Scopus İndeksli Yayınlar Koleksiyonu