The first countrywide monitoring of selected POPs: Polychlorinated biphenyls (PCBs), polybrominated diphenyl ethers (PBDEs) and selected organochlorine pesticides (OCPs) in the atmosphere of Turkey

dc.authorid0000-0001-6737-3475en_US
dc.contributor.authorKurt Karakuş, Perihan Binnur
dc.contributor.authorUgranli-Cicek, Tugba
dc.contributor.authorSofuoglu, Sait C.
dc.contributor.authorCelik, Halil
dc.contributor.authorGungormus, Elif
dc.contributor.authorBirgül, Aşkın
dc.date.accessioned2021-03-20T20:13:20Z
dc.date.available2021-03-20T20:13:20Z
dc.date.issued2018
dc.departmentBTÜ, Mühendislik ve Doğa Bilimleri Fakültesi, Çevre Mühendisliği Bölümüen_US
dc.description.abstractAtmospheric levels of 43 PCBs, 22 OCPs, and 14 PBDEs were determined in 16 cities at urban and rural sites by passive sampling to generate the first large-scale nationwide dataset of POP residues in Turkey's atmosphere. Sampling campaign was performed from May 2014 to April 2015 with three-month sampling periods at locations on east-west and north-south transects through the country to investigate seasonal and spatial variations, including long range atmospheric transport (LRAT). Factor analysis was conducted to infer on the potential sources. Overall average E43PCB5 concentration was 108 +/- 132 pg/m(3). PCB-118 (26.3 +/- 44.6 pg/m(3)) was the top congener, and penta-CBs had the highest contribution with 54.3%. EDDTs had the highest annual mean concentration with 134 +/- 296 pg/m(3) among the OCP groups among which the highest concentration compound was pp-DDE (97.6 +/- 236 pg/m(3)). Overall average concentration of EIRBDEs was 191 +/- 329 pg/m(3) with the highest contribution from BDE-190 (42%). Comparison of OCPs and PCBs concentrations detected at temperatures which were above and below annual average temperature indicated higher concentrations in the warmer periods, hence significance of secondary emissions for several OCPs and E.43PCBs, as well as inference as LRAT from secondary emissions. The first nationwide POPs database constructed in this study, point to current use, local secondary emissions, and LRAT for different individual compounds, and indicate the need for regular monitoring.The first country-wide passive sampling of selected POPs showed no unequivocal trends reflecting transitional location of Turkey.en_US
dc.description.sponsorshipTurkish Scientific and Technological Resarch Council (TUBITAK) [112Y314]; TUBITAKTurkiye Bilimsel ve Teknolojik Arastirma Kurumu (TUBITAK) [21514107-221.01-8290]en_US
dc.description.sponsorshipThis work was supported by Turkish Scientific and Technological Resarch Council (TUBITAK) for the financial support (Grant # 112Y314). Dr. Henry Alegria was financially supported by TUBITAK as a visiting scientist (Grant #21514107-221.01-8290). We thank all volunteers who helped us to deploy the samplers and more importantly for taking care of the samplers during the course of the study.en_US
dc.identifier.doi10.1016/j.atmosenv.2018.01.021en_US
dc.identifier.endpage165en_US
dc.identifier.issn1352-2310
dc.identifier.issn1873-2844
dc.identifier.scopusqualityQ1en_US
dc.identifier.startpage154en_US
dc.identifier.urihttp://doi.org/10.1016/j.atmosenv.2018.01.021
dc.identifier.urihttps://hdl.handle.net/20.500.12885/844
dc.identifier.volume177en_US
dc.identifier.wosWOS:000428095500015en_US
dc.identifier.wosqualityQ1en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.institutionauthorKurt Karakuş, Perihan Binnur
dc.language.isoenen_US
dc.publisherPergamon-Elsevier Science Ltden_US
dc.relation.ispartofAtmospheric Environmenten_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.subjectPCBsen_US
dc.subjectOCPsen_US
dc.subjectPBDEsen_US
dc.subjectPassive samplingen_US
dc.subjectUrban and ruralen_US
dc.subjectTurkeyen_US
dc.titleThe first countrywide monitoring of selected POPs: Polychlorinated biphenyls (PCBs), polybrominated diphenyl ethers (PBDEs) and selected organochlorine pesticides (OCPs) in the atmosphere of Turkeyen_US
dc.typeArticleen_US

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