Investigation of the surface properties of dibutyl amine modified poly(styrene) based polymer by inverse gas chromatography method

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dc.authorid0000-0003-4765-1102en_US
dc.contributor.authorAdıgüzel, Ayşegül Çiğdem
dc.contributor.authorKorkmaz, B.
dc.contributor.authorCakar, F.
dc.contributor.authorCankurtaran, O.
dc.contributor.authorSenkal, B. F.
dc.date.accessioned2021-03-20T20:09:11Z
dc.date.available2021-03-20T20:09:11Z
dc.date.issued2021
dc.departmentBTÜ, Mühendislik ve Doğa Bilimleri Fakültesi, Kimya Bölümüen_US
dc.description.abstractIn the present study, poly(vinyl benzyl chloride) (PVBC) was prepared by the radical polymerization method. Then, PVBC was reacted with dibutyl amine to obtain tertiary amine-modified poly(styrene) based polymer (PVBC-Dibutyl amine) and the resulting polymer was characterized. Surface properties of the polymer were investigated by inverse gas chromatography method at infinite dilution region. For this purpose, the retention diagrams of carefully selected polar and non-polar solvents (probes) on PVBC-Dibutyl amine were obtained over a temperature range from 30 to 50 degrees C. By using the diagrams, the dispersive component of the surface free energy of the polymer surface was calculated for the studied temperatures by two different methods. The specific enthalpy of adsorption and the specific component of the adsorption free energy of solvents on PVBC-Dibutyl amine which are adsorption thermodynamic parameters were determined for each solvent used. Using the adsorption data, Lewis acid and Lewis base parameters of PVBC-Dibutyl amine surface were calculated. The obtained parameters reflected that surface of PVBC-Dibutyl amine exhibited a basic behavior. Considering the values in the literature, the effect of dibutyl amine moieties in the structure of poly(styrene) based polymer PVBC-Dibutyl amine on the dispersive surface free energy and acid-base parameters of poly(styrene) was discussed.en_US
dc.description.sponsorshipYildiz Technical University Scientific Research Projects Coordination DepartmentYildiz Technical University [FDK-2018-3502]en_US
dc.description.sponsorshipThis research has been supported by Yildiz Technical University Scientific Research Projects Coordination Department. Project Number: FDK-2018-3502en_US
dc.identifier.doi10.1007/s10965-021-02449-6en_US
dc.identifier.issn1022-9760
dc.identifier.issn1572-8935
dc.identifier.issue3en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.urihttp://doi.org/10.1007/s10965-021-02449-6
dc.identifier.urihttps://hdl.handle.net/20.500.12885/284
dc.identifier.volume28en_US
dc.identifier.wosWOS:000617125700001en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.institutionauthorAdıgüzel, Ayşegül Çiğdem
dc.language.isoenen_US
dc.publisherSpringeren_US
dc.relation.ispartofJournal Of Polymer Researchen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectFunctional polymeren_US
dc.subjectInverse gas chromatographyen_US
dc.subjectSurface characteristicsen_US
dc.subjectDispersive surface free energyen_US
dc.subjectAcid-base propertiesen_US
dc.titleInvestigation of the surface properties of dibutyl amine modified poly(styrene) based polymer by inverse gas chromatography methoden_US
dc.typeArticleen_US

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