UNTANGLING THE INHIBITION EFFECTS OF ALIPHATIC AMINES ON SILVER CORROSION: A COMPUTATIONAL STUDY
Yükleniyor...
Tarih
2017
Yazarlar
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Acad Sciences Moldova, Inst Chemistry
Erişim Hakkı
info:eu-repo/semantics/openAccess
Özet
The topic of corrosion inhibition of different metals by organic compounds has been the focus of intense scrutiny for decades. The enormity of the problem is reflected in the need to understand the underlying inhibition mechanisms of such compounds, one of which is the class of aliphatic amines. Electrochemical measurements represent protective effect of these compounds at ever-increasing levels of detail but these methods lack the resolution to represent inhibition efficiency-molecular structure relations adequately. In this study, the dependence of inhibition effect of four aliphatic amines (methylamine, ethylamine, n-propylamine, and n-butylamine), on their molecular and electronic structure is analysed using quantum chemical calculations. The obtained results of these calculations were found to be consistent with the experimental findings.
Açıklama
Anahtar Kelimeler
corrosion inhibitor, silver, aliphatic amines, density functional theory
Kaynak
Chemistry Journal Of Moldova
WoS Q Değeri
N/A
Scopus Q Değeri
Q4
Cilt
12
Sayı
2
