Controlled Synthesis of Hyperbranched Polymers by TEMPO-Mediated Radical Polymerization

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dc.authorid0000-0003-1858-0691en_US
dc.contributor.authorÇiftçi, Mustafa
dc.date.accessioned2021-03-20T20:12:48Z
dc.date.available2021-03-20T20:12:48Z
dc.date.issued2020
dc.departmentBTÜ, Mühendislik ve Doğa Bilimleri Fakültesi, Kimya Bölümüen_US
dc.description.abstractBranched polymers with tunable branching densities are prepared by TEMPO-mediated radical polymerization. Thus, styrene is copolymerized with 4-methacryloyloxy-2,2,6,6-tetramethylpiperidine-1-oxyl (TEMPO methacrylate) by using 2,2'-azobis(2-methylpropionitrile) (AIBN) as initiator at 125 degrees C. The method is based on the use of TEMPO methacrylate as branching unit that possessing a nitroxyl stable radical moiety as propagation radical trap and a polymerizable methacrylate group. Depending on the concentration of TEMPO methacrylate and polymerization time, hyperbranched polymers with different branching densities are obtained.en_US
dc.identifier.endpage762en_US
dc.identifier.issn0914-9244
dc.identifier.issue6en_US
dc.identifier.scopusqualityQ4en_US
dc.identifier.startpage759en_US
dc.identifier.urihttps://hdl.handle.net/20.500.12885/703
dc.identifier.volume32en_US
dc.identifier.wosWOS:000514218400001en_US
dc.identifier.wosqualityQ4en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.institutionauthorÇiftçi, Mustafa
dc.language.isoenen_US
dc.publisherTechnical Assoc Photopolymers,Japanen_US
dc.relation.ispartofJournal Of Photopolymer Science And Technologyen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.subjectHyperbranched polymersen_US
dc.subjectNMRPen_US
dc.subjectControlled/living polymerizationen_US
dc.titleControlled Synthesis of Hyperbranched Polymers by TEMPO-Mediated Radical Polymerizationen_US
dc.typeArticleen_US

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