Orthogonal synthesis and modification of hyperbranched polymers via different colors of light

Basit Öğe Kaydı
dc.authorid0000-0003-1858-0691
dc.contributor.authorKokcu, Esra
dc.contributor.authorCiftci, Mustafa
dc.contributor.authorTasdelen, Mehmet Atilla
dc.date.accessioned2026-02-08T15:14:48Z
dc.date.available2026-02-08T15:14:48Z
dc.date.issued2024
dc.departmentBursa Teknik Üniversitesi
dc.description.abstractA versatile and straightforward approach for the synthesis of functional hyperbranched polymers with tunable properties is represented utilizing a chromatic orthogonal protocol. The method involves the combination of photo-induced electron/energy transfer-reversible addition-fragmentation chain transfer (PET-RAFT) and self-condensing vinyl polymerization (SCVP) under visible light irradiation leading to the formation of hyperbranched polymers with well-defined properties possessing photo-caged diene moieties. Upon UV light irradiation, the remaining photoenol functionality was efficiently activated for the post-functionalization of the synthesized hyperbranched polymers with maleimide functional molecules via Diels-Alder photo-click chemistry. Both low molar mass and polymeric maleimide functional click components, namely N-phenylmaleimide, poly(ethylene glycol)-maleimide and polycaprolactone-maleimide were quantitively attached onto the hyperbranched polymers under ambient conditions. The results obtained from our protocol indicate high efficiency and convenience, offering a straightforward strategy for the design and synthesis of functionalized hyperbranched polymers. The chromatic orthogonal nature of the protocol enables precise control over the modification process, adding versatility to the materials obtained. Overall, this research lays the groundwork for novel pathways in material design, opening new possibilities for advanced materials with tailored properties. image
dc.description.sponsorshipThe Scientific and Technical Research Council of Turkey (TUBITAK) [220Z036]; Scientific and Technical Research Council of Turkey (TUBITAK)
dc.description.sponsorshipThe authors thank The Scientific and Technical Research Council of Turkey (TUBITAK) for financial support (Project no: 220Z036).
dc.identifier.doi10.1002/pol.20240005
dc.identifier.endpage2102
dc.identifier.issn2642-4150
dc.identifier.issn2642-4169
dc.identifier.issue10
dc.identifier.scopus2-s2.0-85186482494
dc.identifier.scopusqualityQ2
dc.identifier.startpage2094
dc.identifier.urihttps://doi.org/10.1002/pol.20240005
dc.identifier.urihttps://hdl.handle.net/20.500.12885/5450
dc.identifier.volume62
dc.identifier.wosWOS:001170161000001
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherWiley
dc.relation.ispartofJournal of Polymer Science
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/openAccess
dc.snmzWOS_KA_20260207
dc.subjectchromatic orthogonality
dc.subjectclick chemistry
dc.subjecthyperbranched polymers
dc.subjectphotopolymerization
dc.titleOrthogonal synthesis and modification of hyperbranched polymers via different colors of light
dc.typeArticle

Dosyalar

Koleksiyon

WoS İndeksli Yayınlar Koleksiyonu
Scopus İndeksli Yayınlar Koleksiyonu