Photoinduced Synthesis of Block Copolymers by Combining Atom Transfer Radical Polymerization and Photoinduced Radical Oxidation/Addition/Deactivation

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dc.authorid0000-0003-1858-0691en_US
dc.contributor.authorÇiftçi, Mustafa
dc.date.accessioned2021-03-20T20:31:04Z
dc.date.available2021-03-20T20:31:04Z
dc.date.issued2018
dc.departmentBTÜ, Mühendislik ve Doğa Bilimleri Fakültesi, Kimya Bölümüen_US
dc.description.abstractA new polymerization mechanistic transformation strategy, combining two different techniques of controlled polymerization modes, namely atom transfer radical polymerization (ATRP) and photoinduced radical oxidation/addition/deactivation (PROAD), is effectively used for the block copolymers’ formation. Thus, mono- or bi- bromide functional polystyrenes (PS-Br or Br-PS-Br) synthesized by light-induced ATRP were used as a macroinitiator on isobutyl vinyl ether in the living cationic polymerization via PROAD process to give the corresponding block copolymers. Thus, depending upon the macroinitiator’s surface, AB/ABA type block copolymers (PS-b-PIBVE or PIBVEb- PS-b-PIBVE) were formed. The final polymers and precursor polymers were characterized by spectral and chromatographic analyses.en_US
dc.identifier.doi10.18596/jotcsa.396618en_US
dc.identifier.endpage478en_US
dc.identifier.issn2149-0120
dc.identifier.issn2149-0120
dc.identifier.issue2en_US
dc.identifier.scopusqualityQ4en_US
dc.identifier.startpage469en_US
dc.identifier.urihttp://doi.org/10.18596/jotcsa.396618
dc.identifier.urihttps://app.trdizin.gov.tr/makale/TXpJME9UZzRPQT09
dc.identifier.urihttps://hdl.handle.net/20.500.12885/1614
dc.identifier.volume5en_US
dc.indekslendigikaynakScopusen_US
dc.indekslendigikaynakTR-Dizinen_US
dc.institutionauthorÇiftçi, Mustafa
dc.language.isoenen_US
dc.relation.ispartofJournal of the Turkish Chemical Society, Section A: Chemistryen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.subjectKimya, Analitiken_US
dc.subjectKimya, Uygulamalıen_US
dc.subjectKimya, İnorganik ve Nükleeren_US
dc.subjectKimya, Tıbbien_US
dc.subjectKimya, Organiken_US
dc.subjectFizikokimyaen_US
dc.subjectSpektroskopien_US
dc.subjectTermodinamiken_US
dc.titlePhotoinduced Synthesis of Block Copolymers by Combining Atom Transfer Radical Polymerization and Photoinduced Radical Oxidation/Addition/Deactivationen_US
dc.typeArticleen_US

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