Spectroscopic and Thermal Study of the Cyanide-Bridged Heteronuclear Compounds [Cd(NH3)(?-3-Aminomethylpyridine)M(?-CN)4]N [M: Pd(II) or Pt(II)]

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dc.contributor.authorKaraagac, Dursun
dc.contributor.authorKurkcuoglu, Gunes Suheyla
dc.date.accessioned2026-02-08T15:14:57Z
dc.date.available2026-02-08T15:14:57Z
dc.date.issued2024
dc.departmentBursa Teknik Üniversitesi
dc.description.abstractNew cyanide-bridged heteronuclear compounds, [Cd(NH3)(mu-ampy)M(mu-CN)(4)](n) [ampy = 3-aminomethylpyridine, M: Pd(II) or Pt(II) (hereafter abbreviated as Cd-M-ampy)] have been prepared in powder form and investigated by utilizing elemental analysis, vibrational (FT-IR and Raman) spectroscopy, and thermal analysis. In our previous work, we synthesized the [Cd(NH3)(mu-ampy)Ni(mu-CN)(4)](n) compound and determined its crystal structure. The results of thermal analysis and vibrational spectroscopic show that the structural characteristics of Cd-Ni-ampy and Cd-M-ampy [M: Pd(II) or Pt(II)] compounds are analogous to each other. In these compounds, while the sphere of the center of the M(II) ion has a square pyramidal geometry, the coordination sphere of the Cd(II) ion is identified to have a distorted octahedral geometry. While one amine, one ampy, and four cyanide ligands coordinate to the Cd(II) ion, a three-dimensional coordination polymer forms by the coordination of these ligands to the Cd(II) and M(II) ions. Thermal degradation of the compounds occurs in two steps: degradation of ampy and amine ligands and release of the cyanide groups.
dc.description.sponsorshipEskiscedil;ehir Osmangazi University, Scientific Research Unit [2022-2561]
dc.description.sponsorshipThis work has been financially supported by Eski & scedil;ehir Osmangazi University, Scientific Research Unit. (project No. 2022-2561).
dc.identifier.doi10.1007/s10812-024-01791-z
dc.identifier.endpage843
dc.identifier.issn0021-9037
dc.identifier.issn1573-8647
dc.identifier.issue4
dc.identifier.scopus2-s2.0-85204143735
dc.identifier.scopusqualityQ4
dc.identifier.startpage835
dc.identifier.urihttps://doi.org/10.1007/s10812-024-01791-z
dc.identifier.urihttps://hdl.handle.net/20.500.12885/5529
dc.identifier.volume91
dc.identifier.wosWOS:001313283700004
dc.identifier.wosqualityQ4
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherSpringer
dc.relation.ispartofJournal of Applied Spectroscopy
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzWOS_KA_20260207
dc.subjecttetracyanometallate(II) compounds
dc.subject3-aminomethylpyridine compounds
dc.subjectheteronuclear compounds
dc.subjectcyanide compounds
dc.titleSpectroscopic and Thermal Study of the Cyanide-Bridged Heteronuclear Compounds [Cd(NH3)(?-3-Aminomethylpyridine)M(?-CN)4]N [M: Pd(II) or Pt(II)]
dc.typeArticle

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