Thermodynamic studies on tert-amine modified polystyrene based polymer/solvent systems by inverse gas chromatography method

dc.authorid0000-0003-4765-1102en_US
dc.contributor.authorAdıgüzel, Ayşegül Çiğdem
dc.date.accessioned2022-08-05T13:28:26Z
dc.date.available2022-08-05T13:28:26Z
dc.date.issued2021en_US
dc.departmentBTÜ, Mühendislik ve Doğa Bilimleri Fakültesi, Kimya Bölümüen_US
dc.description.abstractIn the present work, vinyl benzyl chloride (VBC) was polymerized by using free radical polymerization. The obtained PVBC was reacted with dibutyl amine to obtain tertiary amine modified polystyrene based polymer (PVBC-Dibutyl amine). The inverse gas chromatography (IGC) method was used to examine the thermodynamic properties of the polymer. Firstly, the retention diagrams of some polar and non-polar solvents on PVBC-Dibutyl amine were obtained over a temperature range from 135 to 160 degrees C. Then, the thermodynamic parameters, including Flory-Huggins interaction parameter, weight fraction activity coefficient, partial molar heat of sorption, and partial molar heat of mixing were determined via interactions between the polymer and selected solvents at infinite dilution. The results reveal that the alkanes are poor solvents for the polymer whereas n-butyl acetate, i-butyl acetate, ethyl acetate, n-propylbenzene, i-propylbenzene, and ethylbenzene are moderately solvents in the studied temperature range.en_US
dc.identifier.doi10.14744/sigma.2021.00029en_US
dc.identifier.endpage421en_US
dc.identifier.issn1304-7205
dc.identifier.issn1304-7191
dc.identifier.issue4en_US
dc.identifier.startpage414en_US
dc.identifier.urihttps://hdl.handle.net/20.500.12885/2025
dc.identifier.volume39en_US
dc.identifier.wosqualityN/Aen_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.institutionauthorAdıgüzel, Ayşegül Çiğdem
dc.language.isoenen_US
dc.publisherYıldız Teknik Üniversitesien_US
dc.relation.ispartofSIGMA JOURNAL OF ENGINEERING AND NATURAL SCIENCES-SIGMA MUHENDISLIK VE FEN BILIMLERI DERGISIen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.subjectInverse gas chromatographyen_US
dc.subjectThermodynamicsen_US
dc.subjectPolystyrene based polymeren_US
dc.titleThermodynamic studies on tert-amine modified polystyrene based polymer/solvent systems by inverse gas chromatography methoden_US
dc.typeArticleen_US

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