Flexible Semicrown Ether-Linked Symmetric Cationic Gemini Surfactants: Synthesis and Evaluation as Catalysts for Acceleration of Diastereoselective [3+2] Cycloaddition Reaction in Reversed Phase Micellar Media
Küçük Resim Yok
Tarih
2019
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Wiley
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
Novel cationic gemini surfactants with a hydrophilic oligo-oxyethylene spacer group were synthesized and their physicochemical properties were identified. Computational studies for these compounds were also performed; molecular geometry, frontier molecular orbitals, and quantum chemical parameters were calculated using density functional theory (DFT). After exploration for catalytic activity, it was found that these surfactants can efficaciously accelerate the [3 + 2] cycloaddition reactions in reversed phase micellar media.
Açıklama
Anahtar Kelimeler
Synthesis, Cationic gemini surfactants, Micellar catalysis, Cycloaddition
Kaynak
Journal Of Surfactants And Detergents
WoS Q Değeri
Q3
Scopus Q Değeri
Q3
Cilt
22
Sayı
2
