Sustainable synthetic approaches using [C(16)Im][Oxa] as a flexible organocatalyst and DFT studies toward 3,4-dihydropyrimidinones and benzoxazines
Küçük Resim Yok
Tarih
2017
Yazarlar
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Springer Wien
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
Easily accessible 1-hexadecyl-1H-imidazol-3-ium oxalate is highly efficient Bronsted type acidic catalyst for the selected multicomponent one-pot reactions. The short reaction times, easy workup procedures, and green metal-free conditions for the reactions make the protocols more advantageous. Further reactions proceeded smoothly in good to excellent yields with high purity. To investigate mechanism of the multicomponent reactions, DFT calculations were performed.
Açıklama
Anahtar Kelimeler
Mannich reaction, Biginelli reaction, Organocatalysis, Green chemistry, Quantum chemical calculations
Kaynak
Monatshefte Fur Chemie
WoS Q Değeri
Q3
Scopus Q Değeri
Q3
Cilt
148
Sayı
6
