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Öğe Anodic Oxidation of Effluents from Stages of MBR-UF Municipal Landfill Leachate Treatment Plant(Mary Ann Liebert, Inc, 2020) Ukundimana, Zubeda; Kobya, Mehmet; Omwene, Philip Isaac; Gengec, Erhan; Can, Orhan TanerThis study used boron-doped diamond electrode on niobium substrate (Nb/boron-doped diamond [BDD]) for the anodic oxidation of landfill leachate in a batch reactor. Raw leachate and biologically pretreated effluent samples were collected from each step of the existing unit operation of a municipal landfill leachate treatment plant (Kocaeli-Turkey). The influence of parameters, such as treatment time, initial pH (3.50-10.0), and applied current density (j = 76-1,060 A/m(2)), on the removal of total organic carbon (TOC), chemical oxygen demand (COD), and ammonium nitrogen (NH4+-N) was assessed. The highest pollutant removal efficiencies were obtained at leachate inherent pH (6.50-8.75), moreover, pollutant removal rates increased with the increase in current density. The NH4+-N removal mainly occurred by indirect oxidation and well fitted second-order kinetics, whereas COD removal followed pseudo first-order kinetics. The optimum current density ensuring simultaneous removal of COD and NH4+-N was 756 and 455 A/m(2)for raw leachate and for pretreated effluents, respectively. Under these optimums, nearly complete NH4+-N removal was attained, while >= 97% removal of TOC and COD was recorded. Herein, we present anodic oxidation as a suitable alternative for treatment of both stabilized raw leachate and effluents from stages of the membrane bioreactor/ultrafiltration treatment plant for the abatement of COD, TOC, and NH4+-N.Öğe High-performance carbon black electrode for oxygen reduction reaction and oxidation of atrazine by electro-Fenton process(Elsevier, 2021) Karataş, Okan; Gengec, Nevin Atalay; Gengec, Erhan; Khataee, Alireza; Kobya, MehmetThe aim of this study is to produce an electrode that can be used in H2O2 production and Electro-Fenton (EF) process by an effective, cheap, and easy method. For this reason, a superhydrophobic electrode with a higher PTFE ratio and high thickness was produced with a simple press. The produced electrode was used in the production of H2O2 and mineralization of Atrazine. First, the effect of pH, cathode voltage, and operation time on H2O2 production was evaluated. The maximum H2O2 concentration (409 mg/L), the highest current efficiency (99.80%), and the lowest electrical energy consumption (3.16 kWh/kg) were obtained at 0.8 V, 7.0 of pH, and 120 min, and the stability of the electrode was evaluated up to 720 min. Then, the effects of the operational conditions (pH, cathode voltage, operating time, and catalyst concentration) in electro-Fenton were evaluated. The fastest degradation of Atrazine (>99%) was obtained at 2.0 V, 3.0 of pH, and 0.3 mM of Fe2+ in 15 min. In the final part of the study, the degradation intermediates were identified, and the characterization of the electrode was evaluated by SEM, XRD, FT-IR, tensiometer, potentiostat, and elemental analyzer.Öğe Peroxydisulfate activation by in-situ synthesized Fe3O4 nanoparticles for degradation of atrazine: Performance and mechanism(Elsevier, 2020) Keyikoğlu, Ramazan; Karataş, Okan; Khataee, Alireza; Kobya, Mehmet; Can, Orhan Taner; Soltani, Reza Darvishi CheshmehHerein activation of persoxydisulfate (PDS) was achieved by in-situ synthesized Fe3O4 nanoparticles (NPs) from a sacrificial iron anode in an electrochemical (EC) cell. The as-synthesized Fe3O4 NPs were characterized to be in spherical and in the nano size. The performance of the process, EC-Fe3O4/PDS, was investigated in terms of atrazine (ATZ) degradation. Optimum process conditions were determined as initial pH of 5, electrolyte (Na2SO4) concentration of 1 mM, a current density of 1.67 A m(-2), PDS concentration of 0.5 mM and initial ATZ concentration of 10 mg L-1. At optimum conditions, the EC-Fe3O4/PDS process could effectively degrade 80% of ATZ in an aqueous solution within a short reaction time of 20 min. The electrical energy consumption of the process was found to be quite low with 0.0307 kWh/m(3). Based on the LC/MS analysis, the degradation pathway of ATZ with seven transformation products was proposed. Finally, a possible mechanism of the EC-Fe3O4/PDS process was put forward, which includes the activation of PDS and the role of radicals in the degradation of ATZ. In conclusion, the combination of Fe3O4 NPs catalyzed PDS oxidation with the EC process was very effective in the degradation of ATZ to dechlorinated final products. The strong synergistic effect makes this process superior to conventional methods due to the high degradation efficiency with low electrical energy and chemical consumption. Application of this method, with very low current density, may not only minimize the electrical energy consumption but also help reduce the sludge production due to the lower iron dissolution.Öğe Phosphorus removal from domestic wastewater in electrocoagulation reactor using aluminium and iron plate hybrid anodes(Elsevier Science Bv, 2018) Omwene, Philip Isaac; Kobya, Mehmet; Can, Orhan TanerThe aim of this study was to investigate the effects of initial pH (pH(i) = 4.0-7.0), current density (j = 10-40 A/m(2)), initial phosphorus (P) concentration (C-i of 5.01-52.13 mg/L) and electrocoagulation (EC) time (t(Ec) = 10-100 min) on phosphorus removal from domestic wastewater by a batch EC reactor using hybrid aluminium (Al)-iron (Fe) anodes and titanium cathode. Phosphorus removal from domestic wastewater containing 52.13 mg/L PO4-P was obtained to be 99.99% at optimum conditions (pH(i) = 4, j = 20 A/m(2) and EC time = 80 min). The energy and electrode consumptions at optimum conditions were calculated as 3.422 kWh/m(3) and 0.328 kg/m(3), respectively. The amount of removed P per electrochemically dissolved total metal electrode (q(e)) was calculated as 55.69 mg P/g, while the dissolved metal to removed phosphorus ratio (M-e/P, mol/mol) was 4.40 (Fe/P = 2.63 and Al/P = 1.77) at optimum conditions. It can be concluded that phosphorus removal by hybrid Al-Fe anodes is as effective as using only Fe or Al anodes as per the results present in literature. In addition, the effluent pH after EC treatment process at optimum conditions was 8.8, hence requiring no pH adjustment before discharge.Öğe A review on treatment of membrane concentrates generated from landfill leachate treatment processes(Elsevier, 2021) Keyikoğlu, Ramazan; Karatas, Okan; Rezania, Hamidreza; Kobya, Mehmet; Vatanpour, Vahid; Khataee, AlirezaLandfill leachate (LL) is highly toxic wastewater and comprises various pollutants such as organic compounds, biological organisms, xenobiotics, heavy metals, inorganic salts, and ammonia. The integration of conventional methods with membrane processes has become indispensable due to the enforcement of stricter regulations for the LL discharge. The integrated membrane technologies achieve a pollutant removal efficiency of higher than 95% with a large volume of treated leachate and a low capital cost investment. However, the drawback of these processes is the production of a membrane concentrate with even more hazardous characteristics. This review presents the state of the art methods along with the recent improvements to the existing processes for the treatment of membrane concentrates. The techniques are mainly divided into two categories of conventional, advanced methods and the hybridization of them. The operating conditions, performances of the individual processes along with wastewater characteristics were summarized in detail. Generally, the leachate concentrate properties such as salinity, COD, BOD5/COD ratio, and toxicity are essential parameters for the selection of appropriate treatment methods. It was found that single treatment processes are not able to reach desirable membrane concentrate treatment and need an engineered combination of these techniques to achieve satisfactory removal efficiencies.Öğe TOC and COD removal from instant coffee and coffee products production wastewater by chemical coagulation assisted electrooxidation(Elsevier Science Bv, 2019) Can, Orhan Taner; Gengec, Erhan; Kobya, MehmetThis paper describes and discusses an investigation into the treatment performance of Boron-Doped Diamond (BDD), N coated Ti (N) and various Mixed Metal Oxide (MMO) anodes after pre-treatment chemical coagulation for total organic carbon (TOC) and chemical oxygen demand (COD) removal from instant coffee and coffee products production wastewater. Firstly, the performance of coagulants, AlCl3,Al-2(SO4)(3), FeCl3 and FeSO4 were investigated. Secondly, the treatment performance of BDD, N and various MMO anodes, the influence of the applied current density and the effect of flow rate for the best-performed electrode were investigated. Also, specific energy consumptions and anode performances were calculated and evaluated for electrooxidation process. At the pre-treatment, among the four coagulants, AlCl3 showed the best performance removing 29% TOC and COD 55%. At the electrooxidation process, BDD electrode achieved the best performance. At the end of the 6 h run period, BDD electrode achieved 95% TOC and 97% COD removal. On the other hand, N and MMO electrodes just removed 13-22% TOC and 25-50% COD respectively. In this study, the BDD electrode performed much better than N and MMO electrodes.
