Effect of monomer partitioning on vinyl acetate-butyl acrylate emulsion copolymers
| dc.contributor.author | Ceylan, Özgür | |
| dc.contributor.author | Yıldırım, Hüseyin | |
| dc.date.accessioned | 2026-02-08T15:05:29Z | |
| dc.date.available | 2026-02-08T15:05:29Z | |
| dc.date.issued | 2023 | |
| dc.department | Bursa Teknik Üniversitesi | |
| dc.description.abstract | Semi-continuous free radical emulsion polymerizations of vinyl acetate and butyl acrylate initiated by a water-soluble (potassium peroxydisulfate, KPS) initiator in the presence of a N-methylol acrylamide (NMA) at 70°C were investigated. 12 different monomer compositions (BuA ratio, from 0/100 to 100/0) were prepared and the effect of Vinyl acetate /Butyl acrylate (Vac/BuA) monomer ratio on viscosity, molecular weights (Mn, Mw, Mv), conversion, and molecular weight distribution were also investigated. It was found that as a protective colloid, N-methylol acrylamide worked perfectly for maintaining emulsion stability. Viscosity and molecular weights were increased with BuA ratio in the synthesized copolymers. High conversion values (above 90%) were reached. It was seen that the molecular weight distributions (PDI) of the synthesized copolymers showed a narrow distribution between 3-5. | |
| dc.identifier.doi | 10.29228/JIENS.66549 | |
| dc.identifier.endpage | 38 | |
| dc.identifier.issn | 2791-7630 | |
| dc.identifier.issue | 1 | |
| dc.identifier.startpage | 27 | |
| dc.identifier.uri | https://doi.org/10.29228/JIENS.66549 | |
| dc.identifier.uri | https://hdl.handle.net/20.500.12885/4710 | |
| dc.identifier.volume | 3 | |
| dc.language.iso | en | |
| dc.publisher | İdris Karagöz | |
| dc.relation.ispartof | Yenilikçi Mühendislik ve Doğa Bilimleri | |
| dc.relation.ispartof | Journal of Innovative Engineering and Natural Science | |
| dc.relation.publicationcategory | Makale - Ulusal Hakemli Dergi - Kurum Öğretim Elemanı | |
| dc.rights | info:eu-repo/semantics/openAccess | |
| dc.snmz | KA_DergiPark_20260207 | |
| dc.subject | Polymer Science and Technologies | |
| dc.subject | Polimer Bilimi ve Teknolojileri | |
| dc.title | Effect of monomer partitioning on vinyl acetate-butyl acrylate emulsion copolymers | |
| dc.type | Article |
