Effect of Water-Reducing Admixtures Having Hybrid Silicon Air-Entraining Surfactants on Some Properties of Concrete Mixtures

dc.authorid0000-0003-0326-5015
dc.contributor.authorEmin, Ayvaz
dc.contributor.authorOzen, Suleyman
dc.contributor.authorMardani-Aghabaglou, Ali
dc.contributor.authorUnlu, Ayda
dc.contributor.authorKapti, Tolga
dc.date.accessioned2026-02-12T21:05:04Z
dc.date.available2026-02-12T21:05:04Z
dc.date.issued2022
dc.departmentBursa Teknik Üniversitesi
dc.description.abstractIn order to improve the fresh properties and freeze-thaw resistance of cementitious systems, water-reducing and air-entraining admixtures are actively used in concrete mixtures. Generally, these mentioned admixtures are added to concrete mixtures as two separate admixtures. In this case, when the properties/compositions of one of the admixtures change, compatibility problems of admixtures may occur with each other or with the cement, and the fresh/hardened properties of the concrete may be adversely affected. In this study, a modified water-reducing admixture with both fluidity and air-entraining properties was produced. The utilization effect of high-range water-reducing admixtures (HRWR) having different ethylene oxide/propylene oxide (EO/PO)-based air-entraining surfactants (AES) on some properties of concrete mixtures was investigated. For this purpose, firstly, hybrid silicone AESs with a silicon content of 20%, 33%, and 38.5% were supplied. Then, HRWRs containing seven different AES were produced by using substitution and synthesis methods. In HRWRs produced by the substitution method, 3 and 5 wt. % of HRWR were substituted with EO/PO-based hybrid silicon AES. In the other method, EO/PO-based hybrid silicon air-entraining macromonomers were bonded to the HRWR at ratios of 1, 3, and 5 wt. % during its synthesis process. Replacing HRWR with hybrid silicone AESs increased admixture demand to provide the target slump value in concrete mixtures. Utilization of AESs containing 20% and 33% silicon in HRWR by the substitution method positively affected the permeability and compressive strength of concrete mixtures, while the rise of this ratio to 38.5% by using the synthesis method did not affect them significantly. The presence of surfactant with 20% silicon in 3% and 5% of the admixture and with 33% silicon in 5% of the admixture positively affected frost resistance of concrete mixtures. However, the use of surfactants with 33% silicon content in 3% of the admixture and 38.5% silicon in 1%, 3%, and 5% of the admixture showed a negative effect on the frost resistance of the mixtures.
dc.description.sponsorshipScientific and Technological Research Council of Turkey (TUBITAK) [1170284 (TEYDEP-1511)]; Bursa Uludag University Science and Technology Centre (BAP) [AYP (MH)-2016/16]
dc.description.sponsorshipThe authors appreciate the contributions of the Scientific and Technological Research Council of Turkey (TUBITAK) and Bursa Uludag University Science and Technology Centre (BAP) under Grant Nos. 1170284 (TEYDEP-1511) and AYP (MH)-2016/16, respectively. The authors would also like to thank Polisan Kimya Company for its kind assistance in providing the surfactants and water-reducing admixtures.
dc.identifier.doi10.1061/(ASCE)MT.1943-5533.0004347
dc.identifier.issn0899-1561
dc.identifier.issn1943-5533
dc.identifier.issue9
dc.identifier.scopusqualityQ1
dc.identifier.urihttps://doi.org/10.1061/(ASCE)MT.1943-5533.0004347
dc.identifier.urihttps://hdl.handle.net/20.500.12885/6773
dc.identifier.volume34
dc.identifier.wosWOS:000825801700020
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.language.isoen
dc.publisherAsce-Amer Soc Civil Engineers
dc.relation.ispartofJournal of Materials in Civil Engineering
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WoS_20260212
dc.subjectAir entraining surfactant (AES)
dc.subjectEthylene
dc.subjectpropylene oxide
dc.subjectWater reducing admixture
dc.subjectPermeability
dc.subjectFreezing thawing
dc.titleEffect of Water-Reducing Admixtures Having Hybrid Silicon Air-Entraining Surfactants on Some Properties of Concrete Mixtures
dc.typeArticle

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