Synthesis of multiarm star block copolymer based on host-guest inclusion complexation

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dc.contributor.authorYiğit, Neşe Çakır
dc.contributor.authorHızal, Gürkan
dc.contributor.authorTunca, Ümit
dc.date.accessioned2026-02-08T15:05:29Z
dc.date.available2026-02-08T15:05:29Z
dc.date.issued2022
dc.departmentBursa Teknik Üniversitesi
dc.description.abstractSupramolecular multiarm star block copolymer ((CD-PEG)p-(Ada-PS)n-polyDVB) was prepared by host-guest interaction of ?-cyclodextrin ( ?-CD) end functionalized polyethylene glycol (?-CD-PEG) and adamantane peripherally functionalized multiarm star polymer ((Ada-PS)n-polyDVB). The ?-CD-PEG was synthesized by copper-catalyzed azide/alkyne cycloaddition reaction (CuAAC) of alkyne functional PEG with mono azide functional ?-CD (?-CD-N3). Adamantane functional polystyrene (Ada-PS) was prepared by atom transfer radical polymerization (ATRP) of styrene (St) and was allowed to react with divinyl benzene (DVB) as a linking agent giving (Ada-PS)n-polyDVB multiarm star polymer. The structures of ?-CD-PEG and (Ada-PS)n-polyDVB multiarm star formation were determined by 1H NMR and GPC. 2D ROESY NMR and DLS analysis of (CD-PEG)p-(Ada-PS)n-polyDVB were carried out to validate the formation of the inclusion complex. The evidence of increased molecular weights and size distributions supported the supramolecular multiarm star block copolymer formation.
dc.identifier.doi10.29228/JIENS.54191
dc.identifier.endpage15
dc.identifier.issn2791-7630
dc.identifier.issue1
dc.identifier.startpage1
dc.identifier.urihttps://doi.org/10.29228/JIENS.54191
dc.identifier.urihttps://hdl.handle.net/20.500.12885/4708
dc.identifier.volume2
dc.language.isoen
dc.publisherİdris Karagöz
dc.relation.ispartofYenilikçi Mühendislik ve Doğa Bilimleri
dc.relation.ispartofJournal of Innovative Engineering and Natural Science
dc.relation.publicationcategoryMakale - Ulusal Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/openAccess
dc.snmzKA_DergiPark_20260207
dc.subjectPolymer Science and Technologies
dc.subjectPolimer Bilimi ve Teknolojileri
dc.titleSynthesis of multiarm star block copolymer based on host-guest inclusion complexation
dc.typeArticle

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