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Öğe An Innovative Passivation Technique for Enhanced Corrosion Resistance of Zinc Coatings(Pleiades Publishing Ltd, 2024) Usta, Ibrahim; Ciftci, Muhammed Furkan; Gur, Emine; Kahveci, HulyanurThis study introduces an innovative passivation technique designed to improve the corrosion resistance of zinc coatings. The impact of varying sodium silicate concentrations (4, 6, and 8 mL/L) and passivation times (30-90 s) was examined in baths containing Cr+3 and Co+3 ions. The 120-h salt spray test results revealed that the optimal corrosion resistance was achieved with a medium sodium silicate concentration of 6 mL/L and a 30-s passivation time. This combination led to a significant improvement in performance, with only 12% white rust observed after 120 h. The study highlights the importance of optimizing treatment parameters to significantly enhance corrosion resistance. Notably, Simonkolleit was obtained at a high concentration of 6 mL/L and a 30-s passivation time, further contributing to the enhanced durability of the coating. These surface enhancements provide a promising approach for achieving durable and more efficient zinc coatings in industrial applications.Öğe Zirconium-based surface treatment for welded aluminium alloys: overcoming phosphating limitations prior to organic coating(Taylor & Francis Ltd, 2026) Ozyurt, Gulcan; Usta, IbrahimThis study evaluates a Zirconium-based conversion coating as an eco-friendly alternative to conventional phosphating for welded aluminium alloys. Conventional phosphating often results in uneven coatings on high-silicon alloys and welded areas, reducing adhesion and corrosion resistance. The proposed chromium-, nickel-, and phosphate-free pretreatment contains hexafluorozirconic acid, organic silanes, stabilisers, and complexing agents, forming a thin, amorphous zirconium oxide layer that enhances paint adhesion and corrosion protection. The coating system was applied to 3103 and 5754 aluminium alloys and evaluated in two configurations: cataphoresis alone and a duplex system of cataphoresis followed by wet paint application. Compared to phosphating, salt spray tests and surface analyses showed that the Zirconium-based treatment provides more uniform coatings, better adhesion, and significantly improved corrosion resistance. These results demonstrate the method's technical effectiveness and environmental compliance, making it a promising surface preparation technique for automotive and industrial applications.












