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    Assessment of house dust trace elements and human exposure in Ankara, Turkey
    (Springer Heidelberg, 2023) Gul, Hatice Kubra; Gullu, Gulen; Babaei, Parisa; Nikravan, Afsoun; Kurt-Karakus, Perihan Binnur; Salihoglu, Guray
    One of the impacts of the COVID-19 pandemic is leading people remain at homes longer than ever. Considering the elongation of the time people spend indoors, the potential health risks caused by contaminants including heavy metals in indoor environments have become even more critical. The purpose of this study was to evaluate the levels and sources of heavy metals in indoor dust, to assess the exposure to heavy metals via indoor dust, and to estimate the associated health risk. The highest median value was measured for Zn (263 mu g g(-1)), while the lowest median concentration value was observed for Cd (0.348 mu g g(-1)). The levels of elements measured in the current study were found to be within the ranges reported in the other parts of the world, mostly close to the lower end of the range. House characteristics such as proximity to the main street, presence of pets, number of occupants, and age of the building were the house characteristics influencing the observed higher concentrations of certain heavy metals in houses. Enrichment factor values range between 1.79 (Cr) and 20.4 (Zn) with an average EF value of 8.80 +/- 6.80 representing that the targeted elements are enriched (EF>2) in indoor dust in Ankara. Positive matrix factorization results showed that the heavy metals in the house dust in the study area are mainly contributed from sources namely outdoor dust, carpets/furniture, solders, wall paint/coal combustion, and cigarette smoke. Carcinogenic and non-carcinogenic risk values from heavy metals did not exceed the safe limits recommended by EPA. The highest carcinogenic risk level was caused by Cr. The risk through ingestion was higher than inhalation, and the risk levels were higher for children than for adults.
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    Phthalates in PET Bottles: Assessment of Human Exposure and Load to Landfills
    (Mehmet Sinan Bilgili, 2022) Gul, Hatice Kubra; Salihoglu, Guray; Goren, Ismail Ethem; Daglioglu, Nebile; Kurt-Karakus, Perihan
    Polyethylene terephthalate (PET) bottles have become an integral part of the packaged water industry, but their release of phthalate acid esters (PAEs) is a threat to human health and to the environment. The omnipresence of phthalates in the environmental compartments results in human exposure via multiple pathways such as dermal, oral and inhalation for prolonged periods. This study aims to investigate the phthalate presence in PET bottles and to assess the health risk of people working in landfills/recycling facilities being exposed to these pollutants through dermal contact. MBP(1604 ng g(-1)) was the most abundant compound detected in PET bottle samples, followed by MEP (1056 ng g(-1)), DEP (413 ng g(-1)), MiPP (216 ng g(-1)), DnBP (189 ng g(-1)), BBP (23.2 ng g(-1)), MDHP (19.5 ng g(-1)), DMiP (16.8 ng g(-1)) and respectively. It is calculated that a total of 200.4, 131.96, 51.66, 23.66, 26.94, 2.443, 2.099 and 2.895 kg of MBP, MEP, DEP, DnBP, MiPP, MDHP, DMiP and BBP, respectively are disposed to the landfills/waste disposal sites through waste PET bottles. Mean concentration based dermal exposure estimated daily intake (EDI), target hazard quotient (THQ) and hazard index (HI) values were calculated. THQ values were determined as 0.007, 0.031, 0.113 for BBP, DEP and DnBP, respectively while HI (<1) indicated that the health risk was acceptable for all subjects. However, it is strongly recommended that regular monitoring of phthalates in PET on market shelves should be done to protect the health of consumers as well as to reduce pthalates loads to the environmental compartments.