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Öğe Novel Adsorbents for Canola Oil Physical Refining: Mesoporous Calcium and Magnesium Silica Aerogel(Wiley-V C H Verlag Gmbh, 2025) Soylu, Tulay Merve; Karakuzu-Ikizler, Burcu; Terzioglu, Pinar; Yucel, SevilThe refining process of edible oil is essential for extending its shelf life by removing contaminants that negatively affect quality and consumer acceptance. This study evaluates the effectiveness of calcium silica aerogel, magnesium silica aerogel, a combination of both, bentonite, Trisyl, and various aerogel combinations in a single-stage physical refining process of crude canola oil. Calcium and magnesium silica aerogels were synthesized via the precipitation method from water glass and subsequently dried under ambient pressure using an air dryer. The synthesized aerogels were characterized using scanning electron microscopy, Fourier-transform infrared spectroscopy, N2 adsorption-desorption analysis and bulk density measurements. The surface areas of the calcium and magnesium aerogels were found to be 45.67 m2/g and 616.46 m2/g, with densities of 0.15 g/cm3 and 0.18 g/cm3, respectively. The adsorption capacities of these adsorbents for free fatty acids, peroxides, and color pigments in crude canola oil were examined. The aerogels reduced free fatty acid levels by 14% to 47%, and their use in the refining process produced oil with a lighter color. Notably, the most effective peroxide removal, reaching 53.4%, was achieved with a 50:50 combination of aerogels. These findings demonstrate the potential of calcium and magnesium silica aerogels as effective adsorbents for removing impurities from edible oils.Öğe Role of magnesium and aluminum substitution on the structural properties and bioactivity of bioglasses synthesized from biogenic silica(Keai Publishing Ltd, 2020) Karakuzu-Ikizler, Burcu; Terzioğlu, Pınar; Basaran-Elalmis, Yeliz; Tekerek, Bilge Sema; Yucel, SevilThe objective of this study was to investigate the effect of magnesium (1 wt%) and aluminum (1 wt%) incorporation on the in vitro bioactivity and biodegradation behavior of 45S5 bioactive glasses synthesized from rice husk biogenic silica. The performance of biogenic silica-based samples was compared well with commercial silica-based counterparts. The in vitro biodegradation behavior of bioactive glasses was evaluated by the weight loss of samples and pH variation in the Tris buffer solution. Based on composition, bioglasses possessed different properties before and after simulated body fluid (SBF) immersion. The incorporation of magnesium (Mg) and aluminum (Al) enhanced the Vickers hardness of bioglasses. All the bioglasses showed the hydroxyapatite layer formation after SBF treatment as confirmed by the dissolution, FTIR, SEM and XRD analysis, however it was more prominent in the rice husk silica-based 45S5 bioglass. The biogenic silica seems to be a promising starting material for bioglass systems to be used in bone tissue engineering applications.












